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Journal : Proceedings of Annual International Conference Syiah Kuala University - Life Sciences

Photocatalytic oxidation in phenol removal using Ru/TiO2 and Ru/Al2O3 catalysts Syaifullah Muhammad; Edy Saputra; Shaobin Wang
Proceedings of The Annual International Conference, Syiah Kuala University - Life Sciences & Engineering Chapter Vol 5, No 1 (2015): Engineering
Publisher : Syiah Kuala University

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Abstract

Ru/TiO2 and Ru/Al2O3 catalyst have been synthesized using impregnation method followed by calcinations at temperature of 550 0C. The synthesized catalysts were characterized by XRD, SEM and EDS. Based on characterization result, the active phase of Ru in form of RuO2 was well coated and dispersed on the support surface. The catalysts were then used in photocatalytic oxidation of phenol in the presence of peroxymonosulphte (PMS) as an oxidant and UV-light from Mercury lamp which is categorized as UV-C, with wave length in range of 200-280 nm. Both catalyst are effective for application of photocatalytic oxidation of phenol in the present PMS and UV. Further, activation of PMS for the production of sulphate radicals for phenol degradation in this study is generated by the interaction PMSCatalyst and PMS-UV. The photocatalytic catalyst of Ru/TiO2 and Ru/Al2O3 can increase the removal efficiency of 10-15%. The activity in phenol removal of Ru/TiO2-PMS-UV is slightly higher than Ru/Al2O3-PMS-UV. Both catalysts also showed good performance in the second and third runs after regeneration for multiple uses. Kinetic studies showed that phenol oxidation on the catalysts, Ru/TiO2 and Ru/Al2O3 in the present of PMS and UV follows the first order reaction.
Phenol degradation on heterogeneous catalytic oxidation by using cobalt-natural zeolite catalyst Syaifullah Muhammad; Edy Saputra; Shaobin Wang; Moses O. Tadé
Proceedings of The Annual International Conference, Syiah Kuala University - Life Sciences & Engineering Chapter Vol 1, No 2 (2011): Engineering
Publisher : Syiah Kuala University

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Abstract

Two types of catalysts based on Indonesia Natural Zeolite (INZ) and Australia Natural Zeolite (ANZ) were prepared by impregnation of 5 % of active metal cobalt. The synthesized catalysts were calcined in air at 5500C for 6 hours. The catalysts were then used to degrade phenol concentration in heterogeneous catalytic oxidation with the presence of oxone as peroxymonosulphate source. The catalysts were also characterized by several techniques such as SEM, EDS and N2 adsorption. It was found that Co-INZ and Co-ANZ are effective catalyst in activation of peroxymonosulphate to produce sulphate radicals to degrade phenol concentration. In reaction test of 5 hours, with condition of 25 ppm phenol, 0.2 g catalyst loading, 1 gram oxone, 250C and stirring speed of 400 rpm, Co-INZ and Co-ANZ could reduce phenol up to 100% and 70% respectively. Further, several parameters such as amount of catalyst loading, phenol concentration, oxidant concentration and temperature are found as key factors in phenol degradation. Moreover, based on the trend of phenol degradation following by kinetic study, it was proved that the pseudo first order kinetics would fit to phenol oxidation with the rate constants of 0.0106 and for 0.0033 Co-INZ and Co-ANZ respevtively
Co-Authors Abdullah Syafi’i Ade Anggriawan Affananda Taufik Agustinus Lamhot Viraro Ahmad Fadli Ahmad Zaki Al Qarni Putra Aldi Okta Priyatna Amin Fitra Amir Awaluddin Andes Sagita Arbhy Indera Ikhwansyah Arif Kurnia Arosyidin Arosyidin Bahruddin Chairul Chairul Charismayani Charismayani David Andrio Delvi Yolanda Denny Elisabet Situmeang Desly Fadilla Simbolon Eka Putri Sriandriani Eka Trisnawati Ekadian Lestari Simatupang Ekky Wahyudi Enang Vovilya Eri Kaiyul Erlisa Yanuari Putri Evelyn Evelyn Farhiz Lagan Febrian Adhitya Fenny Lasma Hilde S Fitriani Fitriani Fitry Rahmah Ganis Kharisma Wiranti Genardus Oktavri Sijabat Gusti Ayu Nurjanah Hade Karimata Hafizah Heru Kristianto Hery Fiza Simarmata Ilok Dianggoni Imelda Dewi Agusti Inget Yester Yunanda Irdoni Irdoni Ismeddiyanto Ismeddiyanto Ismi Siska Rahmayani Jhon Armedi Pinem Jhon Fery Marihot Tua S Kartika Pratama Syafitri Khairat Khairat Komalasari Komalasari Lita Darmayanti Lora Mona Tambunan M Arief Riandy M. Wahyu Nugraha Magfirah Marihot Danield Vyendri Simatupang Miguel Felix Wijaya Mohd Fajri Amrullah Monita Olivia Moses O. Tadé Muhammad Rahman Mustapa Ardi Nani Agustina Nazily Haryati Niko Rizaldi Nissa Aqhilla Nova Dwi Safitir Novi Purnama Nuraina Siregar Nurhasanah Nurhasanah Nurlis Nurlis Nurul Afifah Peji Nopeles Rahman Fikri Redol Sianturi Reno Susanto Rio Akbar Rio Saputra Rizaldi Riski Irawan Robi Maulana Rozanna Sri Irianty Shaobin Wang Shaobin Wang Sri Meilani Sri Ulina Beru Ginting Subangkit Julio Jaya SYAIFUL BAHRI Syaifullah Muhammad Syaifullah Muhammad Syarfi Daud Syarfi Syarfi Syelvia Putri Utami Tarsensius Wabady Happy Limbong Tejo Yulandi Tresia Monika Natalia Sinaga Trisuciati Syahwardini Utama, Panca Setia Viqrie Wahyudi Wahyu Muhammad Firdaus Wahyuni Zumara Wali Ara Widya Yoesepha Windy Nila Hakim Yelmida Azis Yudhi Salman Dwi Satya Yuliati Eka Putri Yunita Selonika Zuchra Helwani Zultiniar Zultiniar