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Comparison of Phytoremediation and Filtration for Diamond-mine-tailings Water Treatment Noor, M. Hafidhuddin; Rahman, Mijani; Gazali, Akhmad; Kania, Nia; Rahma, Aulia; Rampun, Erdina L.A.; Pratiwi, Amalia E.; Elma, Muthia
Makara Journal of Technology Vol. 24, No. 1
Publisher : UI Scholars Hub

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

The water pollution caused by diamond mine activities can kill aquatic life. In this work, we used phytoremediation and filtration to treat pond water polluted by the tailings of a diamond mine located in South Kalimantan, Indonesia. Einchhornia crassipes (water hyacinth) was utilized as the biomass for the phytoremediation process. Gravel (10–15 mm) and sand (0.1–1 mm) were used as filter media in the simple filtration setup, using an up-flow system (bottom to top). In the experiment, 16 L of diamond tailing water was poured into five phytoremediation reactors (each 60 L in volume), which were then tested over seven days. A pretreatment analysis of the tailings water showed that its biochemical oxygen demand (BOD) of 8.9 mg L−1 and chemical oxygen demand (COD) of 22 mg L−1 exceeded the national maximum standards of 2 mg L−1 and 10 mg L−1, respectively. The experimental results demonstrate that both phytoremediation and filtration could increase the dissolved oxygen concentration (4.7 mg.L−1) and reduce the BOD (3.2 mg.L−1), COD (6.5 mg.L−1), Fe (0.6 mg.L−1), Mn (0.16 mg.L−1), and ammonia (0.63 mg.L−1) concentrations from those measured in the raw diamond-mine-tailings water. The phytoremediation performance was better than that of filtration. The COD values were successfully reduced to the permissible limit, although the other parameters still failed to meet the government water quality regulation requirements.
IRON ADSORPTION IN PEAT WATER BY SAGO WASTE ACTIVATED CARBON Awali Sir Kautsar Harivram; Isna Syauqiah; Muthia Elma; Erdina Lulu Atika Rampun; Dina Amryna Chairul Putri; Namira Ghina Safitri
Konversi Vol 11, No 2 (2022): OKTOBER 2022
Publisher : Universitas Lambung Mangkurat

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20527/k.v11i2.13752

Abstract

In South Kalimantan, peat water is the main water sources for local people. But peat water has high iron content. It cannot be consumed directly and need further treatment. Adsorption is the most common technology to treat peat water. The goal of this research is to study sago waste adsorbent for iron removal in peat water. Citric acid was employed as activating agent in the sago waste activated carbon adsorbent fabrication. Carbonization process was done at 300 ℃ with 70, 80, 90, 100, 110 and 120 minutes of time variation. After treatment using the adsorbent, iron content was tested via Atomic Absorption Spectrophotometry (AAS). While, Fourier Transform Infra-Red (FTIR) were carried out to investigate the functional groups of sago pith waste activated carbon (SPWAC) and sago pith waste unactivated carbon (SPWUC). The experiment results show iron could be removed until 82% with iron concentration of 0.05 mg/l at 80 minutes. SPWAC and SPWUC have functional groups such as alkenes (C-H and C=C), carbonyl (C=O and C-O) and hydroxyl (O-H). Fe concentrations are still meet water quality standard according to No. 492/Menkes/PER/IV/2010 which is 0.3 mg/L. Therefore, adsorption uses sago pith waste activated carbon is an effective and inexpensive water treatment.
Organo-Silica Membrane Prepared from TEOS-TEVS Modified with Organic-Acid Catalyst for Brackish Water Desalination Muthia Elma; Aptar Eka Lestari; Anna Sumardi; Zaini Lambri Assyaifi; Adi Darmawan; Dwi Rasy Mujiyanti; Isna Syauqiah; Aulia Rahma; Linda Suciwati; Yanti Mawaddah
Jurnal Rekayasa Kimia & Lingkungan Vol 16, No 1 (2021): Jurnal Rekayasa Kimia & Lingkungan (June, 2021)
Publisher : Chemical Engineering Department, Syiah Kuala University, Banda Aceh, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (864.146 KB) | DOI: 10.23955/rkl.v16i2.18107

Abstract

The sol gel process is one of the processes used in the manufacture of thin films on membranes because it can control the pore size in the resulting silica matrix. In addition, another way to build membrane size can be done by adding catalysts and precursors to be used. In this study, using a combination of tetraethyl ortho silicate (TEOS) and triethoxy vinyl silane (TEVS) precursors and citric acid as a catalyst to produce a silica matrix with mesoporous size so that it is suitable for application in the desalination process. The organo silica membrane was calcined at 350 ° C for 1 hour using the RTP calcination technique under vacuum, thus preventing the decomposition of carbon in the silica matrix. The membrane was dipcoated 4 times to obtain 4 layers. The FTIR (Fourier-transform Infrared Spectroscopy) test was carried out to see the functional groups on xerogel, namely silanol, siloxane and carbon. In addition, the performance of this membrane is carried out by desalination through pervaporation using 0.3% NaCl feed water with variations in feed air temperature, namely 25 ℃, 40 ℃ and 60 ℃. The resulting flux of air value increased with increasing feed water temperature, namely 6.1; 11.2; and 12.1 kg.m-2h-1 while the resulting salt rejection was 99.72; 99.64 and 99.23%. So that the organo silica membrane is suitable when applied to the desalination process through pervaporation.  
Application of the Composite Hydrotalcite (Mg/Al)/Chitosan as Adsorbent for the Treatment of Raw Water of Municipal Waterworks PDAM Bandarmasih Maulana Wahyu Noor Ramadhan; Chairul Irawan; Hesti Wijayanti; Muthia Elma
Journal of Wetlands Environmental Management Vol 7, No 1 (2019): January-June
Publisher : Center for Journal Management and Publication

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (634.738 KB) | DOI: 10.20527/jwem.v7i1.197

Abstract

Research has been carried out about raw water treatment of PDAM Bandarmasih by hydrotalcite (Mg/Al) + chitosan (shell of haruan and papuyu fish) adsorbent reviews of decreasing dye value (PtCo), iron (Fe), and turbidity. This research intended to  produce drinking water from utilization of fish shell that were still underutilized into chitosan to be matched with hydrotalcite (Mg/Al) with variations of 1, 2 and 3 grams with a duration of 24 hours. The results showed that the decrease in dyestuff value were 96.78%, 95.03% and 92.98%. Persentage decrease in iron (Fe) were 94.38%, 93.78 and 91.87% and percent of turbidity reduction were 97.98%, 79.76% and 76.56%. Best decrease in variations of  hydrotalcite (Mg/Al) + chitosan was 1 gram for a duration of 24 hours which resulted in a decrease in dyestuff, iron and turbidity of 11 PtCo, 0.047 mg/L, 0.76 NTU where the results were appropriate in the drinking water requirements in accordance with the Regulation of the Minister of Health of the Republic of Indonesia no:492/MENKES/PES/IV/2010.
Inovasi Penyisipan Karbon dari Pektin pada Pembuatan Membran Interlayer-free Silika-pektin Amalia Enggar Pratiwi; Muthia Elma; Meilana Dharma Putra; Agus Mirwan; Aulia Rahma; Erdina Lulu Atika Rampun
Jurnal Kimia Sains dan Aplikasi Vol 22, No 3 (2019): Volume 22 Issue 3 Year 2019
Publisher : Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (2567.594 KB) | DOI: 10.14710/jksa.22.3.93-98

Abstract

Water scarcity is the main issues in Indonesia especially for coastal areas. As a consequence, the water has high salinity of >50.000 ppm salt concentration where an appropriate treatment is necessary before consumed. In this case, desalination process could be carried out using inorganic silica membranes. However, during the process the pore of silica membranes were collapsed due to the directly contact of pores to water molecules for a long term performance. Thereby, in this work the innovation of membrane fabrication using carbon templated in silica matrices has been successfully fabricated. Literally, the carbon templates could be improving the membrane hydro-stability. The interlayer-free silica-pectin membrane was fabricated using TEOS as silica precursor and carbon templated from pectin apple. All membranes waere calcined in variance temperature of 300 and 400°C via Rapid Thermal Processing (RTP). The FTIR results show some functionalization of siloxane, silanol and a new bond of silica-carbon. Whereas, the SEM images show the membrane morphology that the membrane not dense and crack-free with thin film's thickness of ~ 1 μm. An excellent condition of interlayer-free silica-pectin membrane was obtained at pectin concentration of 2.5 %wt. (300°C) and 0.5 %wt. (400°C) with highest functionalization of siloxane and silica-carbon bonds. The existence of silica-carbon bonds were capable to enhancing the membrane hydro-stability. In addition, the carbon chains were contributed to form a smaller pores but also robust pore structures. Those fabricated membranes were shown a good promising due to fast and low cost fabrication with high quality to applicate in seawater desalination.
Interlayer-free Membran Silika Pektin untuk Pervaporasi Air Rawa Asin Erdina Lulu Atika Rampun; Muthia Elma; Isna Syauqiah; Meilana Dharma Putra; Aulia Rahma; Amalia Enggar Pratiwi
Jurnal Kimia Sains dan Aplikasi Vol 22, No 3 (2019): Volume 22 Issue 3 Year 2019
Publisher : Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (2440.738 KB) | DOI: 10.14710/jksa.22.3.99-104

Abstract

Wetland in South Kalimantan is one of surface water sources to provide clean water. However, seawater intrusion has spread into the wetland aquifer and reduce the quality of water. Silica-pectin membrane is a promising technology for desalination. The membranes were tested for desalination by pervaporation at room temperature (~25 °C). During pervaporation process, the water contacts to membrane and the separation is started to occurs as vapour phase by maintaining vacuum pressure (~1 bar). The permeate was collected in the cold trap after condensed using nitrogen liquid. The purpose of this research was to investigate the performance of interlayer-free silica pectin membrane for wetland saline water. Experimental results shows the fluxes of membrane are 0.35 and 0.19 kg.m-2 h-1 ( pectin 0%wt); 0.23 and 0.16 kg.m-2 h-1 (pectin 0.1%wt); 0.58 and 3.63 kg.m-2 h-1 (pectin 0.5%wt); 3.40 and 0.12 kg.m-2 h-1 (pectin 2.5%wt) calcined at 300 and 400 °C, respectively. Natural organic matter (NOM) and salt concentration in wetland saline water can reduce the fluxes up to (~98%). Nevertheless, overall salt rejection of membranes achieved >99%. It was found that low calcination gives better performance at high pectin concentration. While pectin concentration was limited at high calcination.
Step-by-Step Fabrication of PVDF-TiO2 Hollow Fiber Membrane and Its Application Desalination of Wetland Saline Water via Pervaporation M. Mahmud; Muthia Elma; Aulia Rahma; Nurul Huda; Riani Ayu Lestari; Awali S. K. Harivram; Erdina L. A. Rampun; Mohd H. D. Othman; Muhammad Roil Bilad
Indonesian Journal of Science and Technology Vol 8, No 3 (2023): (ONLINE FIRST) IJOST: December 2023
Publisher : Universitas Pendidikan Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.17509/ijost.v8i3.63433

Abstract

Wetland water is opted as the source of domestic water supply when the availability of clean fresh water is scarce. Wetland water requires proper treatment due to the high concentration of organic matter and high salinity, particularly in the dry season. This research aims to synthesize, characterize, and investigate the performance of polyvinylidene fluoride (PVDF)-TiO2 hollow fiber membrane for wetland saline water desalination via pervaporation. The PVDF-TiO2 hollow fiber membranes were fabricated through the dry wet spinning method under various air gaps (10, 15, and 20 cm). Then, the resulting membranes were tested in a pervaporation process at temperatures of 25, 40, and 60°C. Results show that the incorporation of TiO2 into the PVDF matrix imparted hydrophilicity properties into the resultant membranes. The presence of TiO2 was confirmed by the TiO2 stretching vibration at 1640 cm-1 (FTIR) and the TiO2 phase at diffraction peaks at 25.5 and 37°. The membranes exhibited the highest water flux (7.48 kg/m2.h) and salt rejection ( 99.5%) at 40°C. Overall, the developed PVDF-TiO2 hollow fiber membranes showed encouraging results and demonstrated their effectiveness for the desalination of wetland saline water.
Co-Authors Adhe Paramita Adi Darmawan Afrisa Noor Hidayanti Agus Mirwan Ahmad Rizali Noor Akhbar Akhbar Akhbar Amalia Enggar Pratiwi Amalia Enggar Pratiwi Anna Sumardi Anna Sumardi Anna Sumardi Anna Sumardi Aptar Eka Lestari Aptar Eka Lestari Aptar Eka Lestari Aptar Eka Lestari Arfa Agustina Rezekiah Assyaifi, Zaini L Aulia Rahma Aulia Rahma Aulia Rahma Aulia Rahma Awali S. K. Harivram Awali Sir Kautsar Harivram Chairul Irawan Chairul Irawan Dewi Puspita Sari Dewi Puspita Sari Dewi Rahmawati Suparsih Dhimas Ari Pratomo Dhiyaur Rahmah Dina Amryna Chairul Putri Dina Naemah Dwi Rasy Mujiyanti Dwi Rasy Mujiyanti Elsa Nadia Pratiwi Era N R Oktaviana Erdina L. A. Rampun Erdina L.A Rampun Erdina Lulu Atika Rampun Erdina Lulu Atika Rampun Erdina Lulu Atika Rampun Erdina Lulu Atika Rampun Fitri Ria Mustalifah Fitri Ria Mustalifah Gazali, Akhmad Hesti Kesumadewi Hesti Wijayanti Isna Syauqiah Isna Syauqiah Isna Syauqiah Isna Syauqiah Isna Syauqiah Lastuti Abubakar Lilis Septyaningrum Lilis Suryani Lilis Suryani Linda Suci Wati Linda Suci Wati Linda Suciwati M. Ihsan M. Mahmud M. Topan Darmawan Mahmud Mahmud Mahmud Mahmud Mahmud Mahmud Marhamah Marhamah Maulana Wahyu Noor Ramadhan Meilana Dharma Putra Mijani Rahman, Mijani Mita Riani Rezki Mohd H. D. Othman Mufidah Nur Amalia Muhammad Hasan Albana Muhammad Roil Bilad Mustalifah, Fitri Ria Namira Ghina Safitri Nia Kania Noor, Ahmad Rizali Noor, M. Hafidhuddin Nor Aldina Norlian Ledyana Sari Nur baity Nur Riskawati Nur, Thoyib Nurhalisah Nurhalisah Nurul Huda Nurul Huda Pratiwi, Amalia E. Pratiwi, Elsa Nadia Rahma, Aulia Rahmawati Rahmawati Rampun, Erdina L.A. Rampun, Erdina Lulu Atika Rezki, Mita Riani Rian Nugraha Putra Riani Ayu Lestari Rosidah Muis Radam Sadidan Rabiah Satria Anugerah Suhendra Sazila K. Rahman SITI FATIMAH Suhendra, Satria Anugerah sunardi sunardi Syarifah Annahdliyah Thoyib Nur Tri Handayani Wahyuddin Wahyuddin Wahyuddin Wahyuddin Yanti Mawaddah Yanti Mawaddah Yanti Mawaddah Yuniarti Yuniarti Yusuf Aziz Zaini Lambri Assyaifi Zaini Lambri Assyaifi Zaini Lambri Assyaifi