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Journal : Jurnal Purifikasi

KAJIAN TEORITIS PEMISAHAN H2S DALAM BIOGAS SECARA ABSORBSI REAKTIF KE DALAM LARUTAN Fe-EDTA MENGGUNAKAN PACKED COLUMN Ali Altway
Purifikasi Vol 10 No 1 (2009): Jurnal Purifikasi
Publisher : Department of Environmental Engineering-Faculty of Civil, Environmental and Geo Engineering. Institut Teknologi Sepuluh Nopember, Surabaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.12962/j25983806.v10.i1.160

Abstract

The presence of H2S in biogas gives dangerous effect on environment; Therefore, H2S must be eliminated from the biogas. The purpose of this research is to analyze theoretically the elimination process by reactive absorption of H2S in biogas into aqueous Fe-EDTA solution in packed column. This research was carried out by developing mathematical model of the process. The interfacial mass transfer phenomena were described by film model equations solved using van Krevelen approximation. Steady state, isothermal condition, and plug-like pattern of gas-liquid flow in packed column were assumed in this study. The model consists of differential mass balance of H2S in gas phase and Fe-EDTA in liquid phase arising system of non-linear first order differential equations solved numerically by Fourth order Runge-Kutta method under Mathlab facility. The system studied consists of a column 10 cm in diameter filled with 1cm raschig rings to the height of 100 cm. The gas flow rate was held constant at GV = 100 mL/s, liquid flow rate L’ was varied 20, 30, and 40 mL/s, pressure P was varied from 1 to 2.5 atm, the concentration of Fe-EDTA in inlet absorbent was varied from 0.02 to 0.06 kmol/m3. The experimental work was also carried out to validate the simulation prediction. The simulation results showed that the percentage of absorbed H2S can be enhanced by decreasing pressure, increasing temperature, liquid flow rate, and Fe-EDTA concentration The trend of pressure and temperature effect on % H2S recovery showed that the absorption process is controlled by the gas resistance. Using column with packing height of 1 meter, gas flow rate of 100 mL/s, using absorbent containing 0.06 kmol/m3 Fe-EDTA with flow rate of 20 mL/s, and at ambient pressure and temperature, the percentage recovery of H2S reached the value of above 99%. The simulation results agree very well with the experimental data within 3% error.
Co-Authors Abdul Hafid Abubakar Tuhuloula Achmad Roesyadi Adi Soeprijanto Aditya Akhmad Sony Afan Hamzah, Afan Afri Dwijatmiko Aisyah Alifatul Altway, Saidah Anggraheny, Nurul Annasit Annasit Atha Pahlevi Ayu Larasati Azka Afuza Bayu Yusuf Budhikarjono, Kuswandi Kusno Dwi Arimbi Wardaningrum Eldira Nindri Wena Endah Prasetyo Rini Eriska Wahyu Kusuma Erlinda Ningsih, Erlinda Fadillatul Taufany Fadlilatul Taufany Faris Adrian Firsta Hardiyanto Gissa Navira Sevie Haqqyana Haqqyana Harahap, A. H. Hendi Riesta Mulya Istiyanie, Dewi Istiyanie, Dewi Junety Monde Juwari Juwari K Kusnaryo K Kuswandi Karnila Willard Koatlely Serpara Kusnarjo Kusnarjo Kuswandi Kuswandi Kuswandi Kuswandi Kuswandi Kuswandi Lailatul Qadariyah Lailatul Qomariyah, Lailatul Lily Pudjiastuti, Lily Ling Ling M Rachimoellah M Rachimoellah Mahfud Mahfud Mahfud Mahfud Margono Margono Medya Ayunda Fitri Merisa Veronika Suparto Meydita, A. D. Miftah Imam Maarif Mochamad Sidiq Muhammad Alraedi Syukharial Muhammad Anshorulloh Mukhlish Muhammad Fadlan Minallah Muhammad Iqbal Musfil AS Nabila Farras Balqis Nadhifa Auria Andini Nonot Soewarno Nora Amelia Novitrie Novitrie, Nora Amelia Nuniek Hendrianie Nur Aini Nadhifah Nur Ihda Farihatin Nisa Nur Ihda Farikhatin Nisa Nur Ihda Farikhatin Nisa Nurkhamidah, Siti Palupi, A. E. Prapti Ira Kumala Sari R. Darmawan Darmawan Rachmaniah, Orchidea Ragilia Rahma Maulidia Renanto Handogo Rendra Panca Anugraha Ruben Leonardo Panjaitan Salasa Ariq Sungkono Samuel Sembiring Siti Machmudah Siti Nurchamidah Siti Nurkamidah Siti Zullaikah Sri Rachmania Juliastuti Sugeng Winardi Suhadi Suhadi Suhadi Suprapto Suprapto Suprapto Suprapto Surya Rachmadani Susianto S Susianto Susianto Susianto Susianto Tantular Nurtono Tri Widjaja Tri Widjaja Trisna Kumala Dhaniswara W Widiyastuti Wahyu Adinda Larasati Widiyastuti Winardi, S. Winardi, Sugeng Wulansari, Dessy Yeni Rahmawati, Yeni Yosita Dyah Anindita Yunita D Indrasari Zulfahmi Hawali