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ARDIANSYAH ARDIANSYAH
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Journal : Konversi

 1 
POTENSI HAYATI SERAT PURUN TIKUS (ELEOCHARIS DULCIS) DALAM PROSES ADSORPSI KANDUNGAN LOGAM BERAT MERKURI (Hg), TSS DAN COD PADA LIMBAH CAIR PERTAMBANGAN EMAS Irawan, Chairul; Ardiansyah, Ardiansyah; Hanan, Naisya
Konversi Vol 3, No 1 (2014): April 2014
Publisher : Universitas Lambung Mangkurat

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20527/k.v3i1.133

Abstract

Abstrak- Aktivitas pertambangan emas di Kalimantan berpotensi menghasilkan limbah yang termasuk dalam Bahan Beracun Berbahaya (B3) seperti merkuri. Upaya yang dilakukan untuk mengatasi pencemaran ini salah satunya adalah dengan metode adsorpsi. Serat purun tikus mengandung selulosa yang cukup tinggi yaitu sekitar 40,92% sehingga dapat dijadikan sebagai adsorben. Tujuan penelitian ini adalah mempelajari kemampuan serat purun tikus sebagai adsorben alami, mempelajari proses pengolahan biokomposit serat purun tikus dengan material nanopartikel besi oksida,dan mengetahui pengaruh hasil penambahan nanopartikel besi oksida untuk membuat biokomposit serat purun tikus dalam upaya menurunkan kandungan logam berat Hg, Total Suspended Solid (TSS)dan Chemical Oxygen Demand(COD) pada limbah cair pertambangan emas. Serat purun tikus (PT) didelignifikasi menggunakan larutan 1% NaOH kemudian PT-D ini dibuat menjadi biokomposit dengan magnet besi oksida nanopartikel menggunakan metode one-pot solvothermal reaction. Biokomposit ini divariasi menjadi dua jenis yaitu tanpa penambahan gugus amina (PT-M) dan dengan penambahan gugus amina (PT-MA). Karakterisasi yang dilakukan terdiri dari uji Scanning Electron Microscopic(SEM) dan X-Ray Diffraction (XRD). Proses adsorpsi dilakukan selama 8 jam dengan kecepatan pengadukan 150 rpm. Analisa setelah adsorpsi menggunakan metode AAS (Atomic Absorption Spectrophotometer) untuk uji kadar Hg, metode titrimetri untuk COD, dan metode gravimetri untuk TSS.Hasil adsorpsi merkuri (Hg), COD, dan TSS paling optimum pada pH 7 dengan keefektifan masing-masing sebesar 65,04%, 80%, dan 81,25%. Kapasitas adsorpsi maksimum PT-D, PT-M, dan PT-MA terhadap Hg masing-masing sebesar 6,504 mg/g, 6,984 mg/g, dan 6,911 mg/g. Penambahan magnet besi oksida nanopartikel dapat memperbesar kemampuan adsorben serat purun tikus. Kata Kunci : adsorpsi, biokomposit, merkuri, PT, COD, TSSAbstract- Activity of gold mining in Kalimantan potentially can give waste that include into  “Bahan Beracun Berbahaya (B3)” such as mercury. An effort to make out this  contamination is adsorption method. Eleocharis dulcis contain high amount of cellulose, about 40,92% so it can be used as an adsorbent. The purpose of this research are studying the capability of eleocharis dulcis as a natural adsorbent, studying the process of biocomposite making from eleocharis dulcis with iron oxide nanoparticle, and studying  the influent of result iron oxide nanoparticle added to biocomposite in order to make a lower amount of heavy metal mercury (Hg), Total Suspended Solid (TSS) dan Chemical Oxygen Demand (COD) in waste water of gold mining. Eleocharis dulcis (PT) through     delignification process use 1% NaOH solution and then  the PT-D is made to become biocomposite with iron oxide nanoparticle apply “one-pot solvothermal reaction” method. The biocomposite have two variation: without amina cluster added (PT-M)  and with amina cluster added (PT-MA). It’s characterization are consist of Scanning Electron Microscope (SEM) and X-Ray Diffraction (XRD). Adsorption process is applied for 8 hours with mixing rate is 150 rpm. Analysis after adsorption process including three methods: AAS (Atomic Absorption Spectrophotometer) method for Hg analysis, titrimetric method for COD, and gravimetric method for TSS.  The result of adsorption process for mercury (Hg), COD, and TSS are optimally at pH 7 which the value of their effectiveness are 65,04%,  80%, and 81,25%. The maximum amount of Hg  adsorption capacity for PT-D, PT-M, and PT-MA respectively are 6,504 mg/g, 6,984 mg/g, and 6,911 mg/g. The addition of iron oxide nanoparticle can increase adsorben capability of eleocharis dulcis. Keywords : adsorption, biocomposite, mercury, PT, COD, TSS
Co-Authors Abd. Rasyid Syamsuri Abdul Rahman Abdullah Abdullah Abdur Rauf, Abdur Achmad Ramadhan Achmad, Isma’il Adinda Suciyandhani Afana Riesma Ila’la, Afana Riesma Afik Hardanto Amaliah, Isma Andi Pasinringi Anggita Rahmadhani Apdila Safitri Arda Arda Arjuna Arjuna Asep Handaya Saputra Asep Saputra Asna Mustofa Atiqa Aulia Azhiimatun Qurrotu A’yuni Bagio Kadaryanto, Bagio Buchori Asyik Budiman, Yosef Satrianus Chairul Irawan Dahlia Dahlia David Kaluge Denny Widhiyanuriyawan Devi Lestari Dewi, Puput Puspita Dwi Intan Rahayu Edy Haryono Eliza, Naila Endang Warih Minarni Eni Sumarni erdiansyah erdiansyah, erdiansyah Evi Deliana HZ Evie Awuy Firman Firman Fitri Diana Wulansari Gandung Sugita Gunawan Gunawan Gusman Lesmana Hamdani Hamdani Handoko, Dody D. Happy Ariyanto Hartinah Hartinah Harun, Asri Martha K. Hasby Syarifuddin Masyhuri, Hasby Syarifuddin Hasiru, Roy Hasniar Hasniar, Hasniar Herdin Muhtarom Herri Novealdi Idha Sari Ilato, Rosman Ilmi, Syaiful Imam Prawiranegara Gani INDIRA PUTRI FAUHAN Indriastuti, K Janur, Nur Akifah Jibril, Hadira Thumaninah Juli Julaiha Jumadi Tangko Kasnaeny Karim, Kasnaeny Khalikussabir, Khalikussabir Krissandi Wijaya Kurniati, Fitrah Laras Cempaka Magvira, Magvira Masrukhi Masrukhi Masrullita, M Masrurodin, Zaenul Melizubaida Mahmud Meriatna Miranti Adelia Afda Moh. Alamsyah Muh Syukri MUHAMMAD AGUS SALIM Muhammad Al-hafiz MUHAMMAD ALI Muhammad Arsyad Suyuti Muhammad Asyraf Al-Kholis Muhammad Fachri Muhammad Rivai Mulyani, Nunung Sri Munawir Munawir Naisya Hanan, Naisya Ni Putu Galuh Megantari Ekaputri, Ni Putu Galuh Nugroho Dewanto Nur Helmi Nurjannah Nurmawati Nasibu Nurul Maulida Alwi Oktavianus Prayitno, Oktavianus Oktawati, Nurul Ovie Panigoro, Meyko Pariyadi, Pariyadi Poloalo, Ayudia Pratama, Aghy Gilar Purnami Purnami Purwoko H Kuncoro, Purwoko H Putri Neva Octavia Putri Rieski Imanda, Putri Rieski Radia Hafid Rafika Ratik Srimurni Rahma Faelasofi, Rahma Rainarli, Ednawati Rais, Amin Rasmiwetti Rasmiwetti, Rasmiwetti Rejebmamet, Rejebmamet Reza Kusuma Nurrohman, Reza Kusuma Rinitha Dinda Safitri, Rinitha Dinda Riswan Berutu Rizki Maryam Astuti Rizky, Robby Rosmaniar Gailea Safriwardy, Ferri Saharuddin Nara Sahnan Rangkuti Salim Said Daulay Sastrio, Sastrio Sedarmayanti, Sedarmayanti Seniati Seniati, Seniati Siswanto, A Siswantoro Siswantoro Siti Ulfatun Najiyyah, Siti Ulfatun Sopan Sofian Sri Wilda Albeta Suci Puji Hadianti Sudirman Sudirman Suharto, Adviansyah Huda Suryati, S Syaharuddin Rasyid Syarwani Canon Taku Nishimura, Taku Taslim, Syafaat triantoro, dony arung Umami, Nia Nurul Usman Moonti Vania Vania Venni Julyandy Putri Waeduramae, Sulaeman Wahyudi David Wardoyo, E Hagni Wargadalem, Farida Ratu Wibowo, Andrianto Heri William Wibowo Yunita Sabrina, Yunita Yusuf Kendek Yusuf Kendek Paluin Zubaidah Zubaidah